Optical constants

Refractive index of GLS - Gallium lanthanum sulphide (CRYSTRAN)

GLS - Gallium lanthanum sulphide: n,k 0.5461–1.71 µm

Data
tabulated n + tabulated k
Range
0.5461–1.71 µm
Points
8
State
crystalline
Licence
CC0-1.0

Plot

Click the plot to set the calculator wavelength.

At one wavelength

Range 0.5461–1.71 µm
Refractive index n
2.49563
Extinction coefficient k
0
Permittivity ε1
6.22815
Permittivity ε2
0
Absorption coefficient α
0 cm⁻¹
Penetration depth δ = λ/(2πk)
— nm
Abbe number Vd
—
Chromatic dispersion dn/dλ
-0.508475 µm⁻¹
Group index ng
2.79441
Group velocity dispersion
— fs²/mm
Dispersion parameter D
— ps/(nm·km)
Photon energy
2.11001 eV

ε = (n + ik)², α = 4πk/λ, ng = n − λ dn/dλ, GVD = λ³/(2πc²) d²n/dλ², D = −(λ/c) d²n/dλ². Group-velocity dispersion is given for formula data only.

Use it in Lightsmith

Load this data in Python, simulate in one more line

pip install lightsmith
import lightsmith as ls

# GLS - Gallium lanthanum sulphide (CRYSTRAN): GLS - Gallium lanthanum sulphide
crystran_gls = ls.fetch_refractiveindex("specs", "CRYSTRAN-optical", "GLS", ref="c5c2f188e848453def5970e347399d653df2ffc2")
print(crystran_gls.range_nm)  # (546.1, 1710.1) nm
eps = crystran_gls.eps([633])  # complex permittivity

Downloads the original record once (pinned to the imported snapshot) and caches it.

Lightsmith is open source (MIT): Mie, T-matrix, BEM, DDA, FDTD, RCWA, TMM, mode solvers and inverse design behind one spec, on CPU or GPU. GitHub.

Comments and conditions

Gallium Lanthanum Sulphide is a radically new chalcogenide glass and a much awaited alternative to toxic Arsenic-based glasses, with an optical transparency from the visible to infrared wavelengths, and thermal stability up to 550oC. In addition, GLS can be melted in a large scale without the need for sealed ampoule processing making GLS production and processing safer and more economical. Equally important, impurity levels, in particular, OH- and SH- absorption bands at around 3 and 4 ìm have been substantially reduced thus increasing performance.
GLS has found use in a wide range of optoelectronic applications and is available as polished optical components, thin and thick films and in optical fibre form.
Gallium Lanthanum Sulphide (GLS) glass is produced by proprietary processes under conditions of the highest purity. Particular effort is made in removing transition metal impurities to a level of better than 1 ppm total metallic impurities with SH- and OH- less than 1 ppm. GLS is routinely processed from ingots of 500 grams. Other glass compositions are available including rare earth doped (Ce, Pr, Nd, Tb, Dy, Ho, Er, Tm, Yb), halide (F, Cl), and Ag doped samples.
REFERENCES:
(1) Petrovich, Hewak et al Journal of Non-Crystalline Solids 326&327 (2003) 93–97°K-1

Properties

density
value: 4040
thermal dispersion
type: constant, value: 75e-06
thermal expansion
value: 10e-06, temperature: 273
hardness
type: Knoop, value: 2.02e9, indenter mass: 0.2
melting point
value: 1103
thermal conductivity
value: 0.43, temperature: 273
youngs modulus
value: 59e9
poissons ratio
value: 0.24
solubility
value: 0

Thermo-optic coefficient

  • dn/dT = 7.50e-05 K⁻¹

References

Cite

Crystran Ltd. The Crystran handbook of infra-red and ultra-violet optical materials (5th edition, 2023); See also Crystran GLS online data sheet; Data from the refractiveindex.info database (M. N. Polyanskiy, Sci. Data 11, 94 (2024), doi:10.1038/s41597-023-02898-2)

Data

Computed on 8 wavelengths, the same grid as the API and the library
GLS - Gallium lanthanum sulphide (CRYSTRAN), GLS - Gallium lanthanum sulphide: n and k versus wavelength
λ (µm)nk
0.54612.5220
0.5792.50
0.64392.4670
0.66782.4580
0.70652.4460
1.0142.3980
1.36732.3790
1.71012.3710

Optical transmission calculator

Free-standing sample in vacuum, normal incidence
Method
Transmittance T
—
Reflectance R
—

Fresnel reflection calculator

Direction
Rp
—
Rs
—
R = (Rp+Rs)/2
—
Phase φp
—
Phase φs
—
Brewster angle θB
—
Critical angle θC
—