Optical constants

Refractive index of CH4 (Methane)

Martonchik and Orton 1994: Liquid at 90 K; n,k 0.002–71.4 µm

Data
tabulated nk
Range
0.002–71.43 µm
Points
43
Temperature
90 K
State
liquid
Licence
CC0-1.0

Plot

Click the plot to set the calculator wavelength.

At one wavelength

Range 0.002–71.43 µm
Refractive index n
1.292
Extinction coefficient k
1.21628e-09
Permittivity ε1
1.66926
Permittivity ε2
3.14286e-09
Absorption coefficient α
0.000260112 cm⁻¹
Penetration depth δ = λ/(2πk)
7.68900e+10 nm
Abbe number Vd
—
Chromatic dispersion dn/dλ
0 µm⁻¹
Group index ng
1.292
Group velocity dispersion
— fs²/mm
Dispersion parameter D
— ps/(nm·km)
Photon energy
2.11001 eV

ε = (n + ik)², α = 4πk/λ, ng = n − λ dn/dλ, GVD = λ³/(2πc²) d²n/dλ², D = −(λ/c) d²n/dλ². Group-velocity dispersion is given for formula data only.

Use it in Lightsmith

Load this data in Python, simulate in one more line

pip install lightsmith
import lightsmith as ls

# CH4 (Methane): Martonchik and Orton 1994: Liquid at 90 K; n,k 0.002–71.4 µm
ch4 = ls.fetch_refractiveindex("organic", "methane", "Martonchik-liquid-90K", ref="c5c2f188e848453def5970e347399d653df2ffc2")
print(ch4.range_nm)  # (2, 71430) nm
eps = ch4.eps([633])  # complex permittivity

Downloads the original record once (pinned to the imported snapshot) and caches it.

Lightsmith is open source (MIT): Mie, T-matrix, BEM, DDA, FDTD, RCWA, TMM, mode solvers and inverse design behind one spec, on CPU or GPU. GitHub.

Comments and conditions

Phase I solid methane at 90 K (-183.15 °C, melting point)
CAUTION: don't rely on interpolated values: Most data points represent values at local maxima or minima

Conditions

temperature
90 K

References

J. V. Martonchik and G. S. Orton. Optical constants of liquid and solid methane. Appl. Opt. 33, 8306-8317 (1994)

Cite

John V. Martonchik and Glenn S. Orton. Optical constants of liquid and solid methane. Applied Optics, 33, 8306 (1994), doi:10.1364/ao.33.008306; Data from the refractiveindex.info database (M. N. Polyanskiy, Sci. Data 11, 94 (2024), doi:10.1038/s41597-023-02898-2)

Data

43 rows as published
CH4 (Methane), Martonchik and Orton 1994: Liquid at 90 K; n,k 0.002–71.4 µm: n and k versus wavelength
λ (µm)nk
0.0021.0010.0
0.05450.8560.2137
0.091.2090.6501
0.11.4480.4853
0.10121.4460.4768
0.10871.5080.3761
0.11621.4720.3225
0.121.4860.3336
0.13371.7040.1814
0.41.30.0
0.58311.2921.237e-09
0.59831.2921.167e-09
0.62151.2911.951e-07
0.66961.294.771e-09
0.68561.292.675e-09
0.70571.298.381e-09
0.71741.291.156e-07
0.72991.299.907e-08
0.78491.2893.995e-08
0.79941.2896.103e-08
0.84181.2894.998e-08
0.86731.2883.311e-07
0.88851.2881.899e-06
0.97421.2884.958e-07
0.98721.2886.281e-07
1.01.2888.313e-07
1.0141.2881.006e-06
1.2351.2871.677e-07
1.2411.2878.425e-08
1.9321.2851.574e-06
1.9531.2858.947e-07
3.291.2430.03198
3.331.2780.07462
3.371.3110.03731
3.431.3010.02132
3.571.3030.01066
7.591.1950.07728
7.691.2750.1706
7.81.3650.07994
8.131.3260.2135
8.261.3320.01067
41.671.2910.0006645
71.431.2920.001442

Optical transmission calculator

Free-standing sample in vacuum, normal incidence
Method
Transmittance T
—
Reflectance R
—

Fresnel reflection calculator

Direction
Rp
—
Rs
—
R = (Rp+Rs)/2
—
Phase φp
—
Phase φs
—
Brewster angle θB
—
Critical angle θC
—