Optical constants

Refractive index of H2O, D2O (Water, heavy water, ice)

Bashkatov and Genina 2003: Water; n 0.225–1.14 µm; 20 °C

Data
formula 5
Range
0.225–1.14 µm
Temperature
293.15 K
State
liquid
Licence
CC0-1.0

Plot

Click the plot to set the calculator wavelength.

At one wavelength

Range 0.225–1.14 µm
Refractive index n
1.33295
Extinction coefficient k
0
Permittivity ε1
1.77676
Permittivity ε2
0
Absorption coefficient α
0 cm⁻¹
Penetration depth δ = λ/(2πk)
— nm
Abbe number Vd
45.608
Chromatic dispersion dn/dλ
-0.0388706 µm⁻¹
Group index ng
1.35579
Group velocity dispersion
59.1111 fs²/mm
Dispersion parameter D
-322.482 ps/(nm·km)
Photon energy
2.11001 eV

ε = (n + ik)², α = 4πk/λ, ng = n − λ dn/dλ, GVD = λ³/(2πc²) d²n/dλ², D = −(λ/c) d²n/dλ². Group-velocity dispersion is given for formula data only.

Use it in Lightsmith

Load this data in Python, simulate in one more line

pip install lightsmith
import lightsmith as ls

# H2O, D2O (Water, heavy water, ice): Bashkatov and Genina 2003: Water; n 0.225–1.14 µm; 20 °C
h2o_d2o = ls.fetch_refractiveindex("main", "H2O", "Bashkatov", ref="c5c2f188e848453def5970e347399d653df2ffc2")
print(h2o_d2o.range_nm)  # (225, 1140) nm
eps = h2o_d2o.eps([633])  # complex permittivity

Downloads the original record once (pinned to the imported snapshot) and caches it.

Lightsmith is open source (MIT): Mie, T-matrix, BEM, DDA, FDTD, RCWA, TMM, mode solvers and inverse design behind one spec, on CPU or GPU. GitHub.

Dispersion formula

Cauchy (formula 5), λ in µm
n=1.31984+0.005190553⁢λ−2.0−0.000256169⁢λ−4.0+9.39388×10-6⁢λ−6.0

Valid from 0.225 to 1.14 µm.

Coefficients as stored
CiValue
C11.31984
C20.005190553
C3-2.0
C4-0.000256169
C5-4.0
C69.39388e-06
C7-6.0

Comments and conditions

High-performance liquid chromatography (HPLC) distilled water at 20.0 °C.

There are typesetting errors in the original paper: In Table 2, the coefficient C must be multiplied by 108 (not 10−8) and the coefficient D must be multiplied by 1012. Additionally, Equation (7) must be multiplied by 1012. With these corrections, and after converting the wavelength to µm, the following expressions can be used to calculate the coefficients of the dispersion formula at any temperature in the 0–100 °C range:

A(t) = 1.3208 − 1.2325×10−5·t − 1.8674×10−6·t2 + 5.0233×10−9·t3
B(t) = 5.2082413×10−3 − 5.179×10−7·t − 2.284×10−8·t2 + 6.9608×10−11·t3
C(t) = −2.5551×10−4 − 1.8341336×10−8·t − 9.172319×10−10·t2 + 2.7729×10−12·t3
D(t) = 9.3495×10−6 + 1.7855×10−3·t + 3.6733×10−1·t2 − 1.2932×101·t3

Conditions

temperature
293.15 K

References

A. N. Bashkatov and E. A. Genina. Water refractive index in dependence on temperature and wavelength: a simple approximation. Proc. SPIE 5068, 393-395 (2003)
  • doi:10.1117/12.518857 <title>Water refractive index in dependence on temperature and wavelength: a simple approximation</title>, SPIE Proceedings (2003)

Cite

Alexey N. Bashkatov and Elina A. Genina. <title>Water refractive index in dependence on temperature and wavelength: a simple approximation</title>. SPIE Proceedings, 393-395 (2003), doi:10.1117/12.518857; Data from the refractiveindex.info database (M. N. Polyanskiy, Sci. Data 11, 94 (2024), doi:10.1038/s41597-023-02898-2)

Data

Computed on 400 wavelengths, the same grid as the API and the library
H2O, D2O (Water, heavy water, ice), Bashkatov and Genina 2003: Water; n 0.225–1.14 µm; 20 °C: n and k versus wavelength
λ (µm)n
0.2251.394818
0.2259171.393855
0.2268381.392915
0.2277621.391997
0.228691.3911
0.2296221.390224
0.2305581.389369
0.2314971.388533
0.2324411.387716
0.2333881.386918
0.2343391.386138
0.2352941.385376
0.2362531.384631
0.2372161.383902
0.2381821.383189
0.2391531.382492
0.2401281.38181
0.2411061.381143
0.2420891.38049
0.2430751.379851
0.2440661.379226
0.245061.378614
0.2460591.378014
0.2470621.377427
0.2480691.376852
0.249081.376288
0.2500951.375736
0.2511141.375195
0.2521371.374665
0.2531651.374145
0.2541961.373635
0.2552321.373135
0.2562721.372644
0.2573171.372163
0.2583651.37169
0.2594181.371227
0.2604751.370772
0.2615371.370325
0.2626031.369886
0.2636731.369455
0.2647471.369032
0.2658261.368615
0.2669091.368206
0.2679971.367804
0.2690891.367409
0.2701861.36702
0.2712871.366638
0.2723921.366262
0.2735021.365891
0.2746171.365527
0.2757361.365168
0.276861.364815
0.2779881.364467
0.2791211.364125
0.2802581.363787
0.28141.363454
0.2825471.363126
0.2836991.362803
0.2848551.362485
0.2860161.36217
0.2871811.36186
0.2883511.361555
0.2895261.361253
0.2907061.360955
0.2918911.360661
0.293081.360371
0.2942751.360084
0.2954741.359801
0.2966781.359522
0.2978871.359245
0.2991011.358972
0.300321.358703
0.3015441.358436
0.3027731.358172
0.3040071.357911
0.3052451.357654
0.3064891.357398
0.3077381.357146
0.3089921.356896
0.3102521.356649
0.3115161.356405
0.3127851.356162
0.314061.355923
0.315341.355685
0.3166251.35545
0.3179151.355217
0.3192111.354987
0.3205121.354758
0.3218181.354532
0.3231291.354307
0.3244461.354085
0.3257681.353864
0.3270961.353645
0.3284291.353429
0.3297671.353214
0.3311111.353
0.332461.352789
0.3338151.352579
0.3351751.352371
0.3365411.352165
0.3379131.35196
0.339291.351756
0.3406731.351555
0.3420611.351354
0.3434551.351155
0.3448541.350958
0.346261.350762
0.3476711.350568
0.3490881.350375
0.350511.350183
0.3519391.349992
0.3533731.349803
0.3548131.349615
0.3562591.349428
0.3577111.349243
0.3591681.349059
0.3606321.348876
0.3621021.348694
0.3635771.348513
0.3650591.348333
0.3665471.348155
0.368041.347978
0.369541.347801
0.3710461.347626
0.3725581.347452
0.3740761.347279
0.3756011.347107
0.3771311.346936
0.3786681.346766
0.3802111.346597
0.3817611.346429
0.3833171.346262
0.3848791.346096
0.3864471.345931
0.3880221.345767
0.3896031.345603
0.3911911.345441
0.3927851.345279
0.3943861.345119
0.3959931.344959
0.3976071.3448
0.3992271.344643
0.4008541.344486
0.4024871.344329
0.4041271.344174
0.4057741.34402
0.4074281.343866
0.4090881.343713
0.4107551.343561
0.4124291.34341
0.414111.34326
0.4157981.34311
0.4174921.342961
0.4191931.342813
0.4209021.342666
0.4226171.34252
0.4243391.342374
0.4260681.34223
0.4278051.342086
0.4295481.341942
0.4312981.3418
0.4330561.341658
0.4348211.341517
0.4365931.341377
0.4383721.341237
0.4401581.341098
0.4419521.34096
0.4437531.340823
0.4455621.340686
0.4473771.340551
0.44921.340415
0.4510311.340281
0.4528691.340147
0.4547151.340014
0.4565681.339882
0.4584281.33975
0.4602961.33962
0.4621721.339489
0.4640561.33936
0.4659471.339231
0.4678451.339103
0.4697521.338976
0.4716661.338849
0.4735881.338723
0.4755181.338597
0.4774561.338473
0.4794021.338349
0.4813551.338225
0.4833171.338103
0.4852871.337981
0.4872641.337859
0.489251.337739
0.4912441.337619
0.4932461.337499
0.4952561.33738
0.4972741.337262
0.49931.337145
0.5013351.337028
0.5033781.336912
0.5054291.336797
0.5074891.336682
0.5095571.336568
0.5116341.336454
0.5137191.336341
0.5158121.336229
0.5179141.336117
0.5200251.336006
0.5221441.335896
0.5242721.335786
0.5264081.335677
0.5285541.335568
0.5307081.33546
0.532871.335353
0.5350421.335246
0.5372221.33514
0.5394111.335035
0.541611.33493
0.5438171.334825
0.5460331.334722
0.5482581.334619
0.5504921.334516
0.5527361.334414
0.5549881.334313
0.557251.334212
0.5595211.334112
0.5618011.334013
0.564091.333914
0.5663891.333816
0.5686971.333718
0.5710151.333621
0.5733421.333524
0.5756781.333428
0.5780241.333332
0.580381.333238
0.5827451.333143
0.5851191.333049
0.5875041.332956
0.5898981.332864
0.5923021.332772
0.5947161.33268
0.5971391.332589
0.5995731.332499
0.6020161.332409
0.6044691.33232
0.6069331.332231
0.6094061.332143
0.6118891.332055
0.6143831.331968
0.6168871.331881
0.6194011.331795
0.6219251.33171
0.6244591.331625
0.6270041.33154
0.6295591.331456
0.6321251.331373
0.6347011.33129
0.6372871.331208
0.6398841.331126
0.6424921.331044
0.645111.330964
0.6477391.330883
0.6503791.330803
0.6530291.330724
0.655691.330645
0.6583621.330567
0.6610451.330489
0.6637391.330412
0.6664441.330335
0.669161.330259
0.6718871.330183
0.6746251.330108
0.6773741.330033
0.6801341.329959
0.6829061.329885
0.6856891.329811
0.6884831.329738
0.6912891.329666
0.6941061.329594
0.6969351.329523
0.6997751.329451
0.7026261.329381
0.705491.329311
0.7083651.329241
0.7112511.329172
0.714151.329103
0.717061.329035
0.7199821.328967
0.7229161.3289
0.7258621.328833
0.728821.328767
0.731791.328701
0.7347731.328635
0.7377671.32857
0.7407731.328505
0.7437921.328441
0.7468231.328377
0.7498671.328314
0.7529221.328251
0.7559911.328188
0.7590721.328126
0.7621651.328064
0.7652711.328003
0.7683891.327942
0.7715211.327882
0.7746651.327822
0.7778221.327762
0.7809911.327703
0.7841741.327644
0.787371.327585
0.7905781.327527
0.79381.32747
0.7970351.327413
0.8002831.327356
0.8035441.327299
0.8068191.327243
0.8101071.327188
0.8134081.327132
0.8167231.327077
0.8200511.327023
0.8233931.326969
0.8267481.326915
0.8301181.326862
0.83351.326809
0.8368971.326756
0.8403081.326704
0.8437321.326652
0.847171.3266
0.8506231.326549
0.8540891.326498
0.857571.326448
0.8610641.326398
0.8645731.326348
0.8680971.326299
0.8716341.32625
0.8751861.326201
0.8787531.326153
0.8823341.326105
0.8859291.326057
0.889541.32601
0.8931651.325963
0.8968051.325916
0.9004591.32587
0.9041291.325824
0.9078131.325778
0.9115131.325733
0.9152271.325688
0.9189571.325643
0.9227021.325598
0.9264621.325554
0.9302371.325511
0.9340281.325467
0.9378351.325424
0.9416561.325381
0.9454941.325339
0.9493471.325297
0.9532161.325255
0.95711.325213
0.9611.325172
0.9649171.325131
0.9688491.32509
0.9727971.32505
0.9767611.32501
0.9807421.32497
0.9847381.324931
0.9887511.324891
0.9927811.324852
0.9968261.324814
1.000891.324775
1.004971.324737
1.009061.3247
1.013171.324662
1.01731.324625
1.021451.324588
1.025611.324551
1.029791.324515
1.033991.324479
1.03821.324443
1.042431.324407
1.046681.324372
1.050951.324336
1.055231.324302
1.059531.324267
1.063851.324233
1.068181.324199
1.072541.324165
1.076911.324131
1.081291.324098
1.08571.324065
1.090131.324032
1.094571.323999
1.099031.323967
1.103511.323935
1.1081.323903
1.112521.323871
1.117051.32384
1.121611.323809
1.126181.323778
1.130771.323747
1.135371.323717
1.141.323687

Optical transmission calculator

Free-standing sample in vacuum, normal incidence
Method
Transmittance T
—
Reflectance R
—

Fresnel reflection calculator

Direction
Rp
—
Rs
—
R = (Rp+Rs)/2
—
Phase φp
—
Phase φs
—
Brewster angle θB
—
Critical angle θC
—